Liquid K–Na Alloy Anode Enables Dendrite‐Free Potassium Batteries

Science Behind the Image

Schematic of making solid‐metal anodes into liquid‐alloy anode to suppress dendrite formation. Dendrites form on Na or K solid surface on charge and grow across the separator to the cathode to give an internal short‐circuit. In contrast, the mixing of Na and K results in a room‐temperature K–Na liquid alloy which allows a dendrite‐free large‐capacity battery. The immiscibility of the liquid K–Na in liquid organic electrolytes offers the possibility of a liquid–liquid anode–electrolyte interface. The three layers top‐to‐bottom represent cathode, electrolyte, and anode.

Authors

TACC

Jo Wozniak


Leigang Xue
Hongcai Gao
Weidong Zhou
Sen Xin
Kyusung Park
Yutao Li
John B. Goodenough